{"id":11562,"date":"2025-07-02T03:24:39","date_gmt":"2025-07-01T19:24:39","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/11562"},"modified":"2025-07-02T03:24:39","modified_gmt":"2025-07-01T19:24:39","slug":"%e7%a0%94%e7%a9%b6%e7%94%b2%e5%9f%ba%e5%90%97%e5%95%89%e6%b0%a7%e5%8c%96%e7%89%a9%e7%9a%84%e7%a7%91%e5%ad%a6%e5%82%a8%e5%ad%98%e6%9d%a1%e4%bb%b6%e5%8f%8a%e5%85%b6%e5%af%b9%e5%82%ac%e5%8c%96%e6%b4%bb","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/11562","title":{"rendered":"\u7814\u7a76\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u7684\u79d1\u5b66\u50a8\u5b58\u6761\u4ef6\u53ca\u5176\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u957f\u671f\u5f71\u54cd"},"content":{"rendered":"
\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u7684\u79d1\u5b66\u50a8\u5b58\u6761\u4ef6\u53ca\u5176\u5bf9\u50ac\u5316\u6d3b\u6027\u7684\u957f\u671f\u5f71\u54cd\u7814\u7a76<\/strong><\/p>\n\u5728\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u6709\u4e00\u79cd\u542c\u8d77\u6765\u6709\u70b9\u201c\u6587\u827a\u8303\u513f\u201d\u7684\u5316\u5408\u7269\u2014\u2014\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\uff08N-Methylmorpholine N-oxide\uff0c\u7b80\u79f0NMO\uff09\u3002\u5b83\u4e0d\u50cf\u785d\u9178\u90a3\u4e48\u9738\u9053\uff0c\u4e5f\u4e0d\u50cf\u6d53\u786b\u9178\u90a3\u6837\u8ba9\u4eba\u671b\u800c\u751f\u754f\uff0c\u4f46\u5b83\u5374\u662f\u4e2a\u4f4e\u8c03\u800c\u5b9e\u7528\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u4f5c\u4e3a\u6709\u673a\u5408\u6210\u4e2d\u5e38\u7528\u7684\u6c27\u5316\u5242\uff0c\u5c24\u5176\u662f\u5728OsO\u2084\u50ac\u5316\u7684\u53cc\u7f9f\u57fa\u5316\u53cd\u5e94\u4e2d\uff0c\u5b83\u662f\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u597d\u642d\u6863\u201d\u3002\u4e0d\u8fc7\uff0c\u8fd9\u4f4d\u597d\u642d\u6863\u4e5f\u6709\u81ea\u5df1\u7684\u813e\u6c14\u548c\u5c0f\u5fc3\u601d\uff0c\u5c24\u5176\u662f\u5728\u50a8\u5b58\u65b9\u9762\u3002\u4eca\u5929\u6211\u4eec\u5c31\u6765\u804a\u804a\uff0c\u5982\u4f55\u8ba9\u8fd9\u4f4d\u201c\u5c0f\u6e05\u65b0\u201d\u4fdd\u6301\u4f73\u72b6\u6001\uff0c\u4ee5\u53ca\u5b83\u7684\u50a8\u5b58\u6761\u4ef6\u5230\u5e95\u4f1a\u5bf9\u50ac\u5316\u6d3b\u6027\u4ea7\u751f\u4ec0\u4e48\u6837\u7684\u957f\u671f\u5f71\u54cd\u3002<\/p>\n
\n\u4e00\u3001\u8ba4\u8bc6\u4e00\u4e0b\uff1a\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u7684\u57fa\u672c\u53c2\u6570<\/h3>\n
\u4e3a\u4e86\u66f4\u597d\u5730\u4e86\u89e3\u5982\u4f55\u4e0eNMO\u76f8\u5904\uff0c\u6211\u4eec\u5148\u6765\u770b\u770b\u5b83\u7684\u57fa\u672c\u201c\u6027\u683c\u201d\uff1a<\/p>\n
\n\n\n\u53c2\u6570<\/th>\n | \u6570\u503c\u6216\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n |
\n\n\u5206\u5b50\u5f0f<\/td>\n | C\u2085H\u2081\u2081NO\u2082<\/td>\n<\/tr>\n |
\n\u5206\u5b50\u91cf<\/td>\n | 117.15 g\/mol<\/td>\n<\/tr>\n |
\n\u5916\u89c2<\/td>\n | \u767d\u8272\u7ed3\u6676\u6027\u7c89\u672b\u6216\u6676\u4f53<\/td>\n<\/tr>\n |
\n\u7194\u70b9<\/td>\n | 120\u2013123\u202f\u00b0C\uff08\u5206\u89e3\uff09<\/td>\n<\/tr>\n |
\n\u6eb6\u89e3\u6027<\/td>\n | \u6613\u6eb6\u4e8e\u6c34\u3001\u3001\uff1b\u5fae\u6eb6\u4e8e<\/td>\n<\/tr>\n |
\npKa<\/td>\n | \u7ea64.8\uff08\u6c34\u6eb6\u6db2\uff09<\/td>\n<\/tr>\n |
\n\u7a33\u5b9a\u6027<\/td>\n | \u5728\u5e72\u71e5\u6761\u4ef6\u4e0b\u7a33\u5b9a\uff0c\u9047\u6e7f\u6613\u6f6e\u89e3<\/td>\n<\/tr>\n |
\n\u50a8\u5b58\u5efa\u8bae<\/td>\n | \u907f\u5149\u3001\u5bc6\u5c01\u3001\u5e72\u71e5\u73af\u5883<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \u4ece\u8fd9\u4e9b\u53c2\u6570\u6211\u4eec\u53ef\u4ee5\u770b\u51fa\uff0cNMO\u867d\u7136\u770b\u8d77\u6765\u633a\u201c\u6e29\u548c\u201d\uff0c\u4f46\u5176\u5b9e\u5bf9\u73af\u5883\u8fd8\u662f\u6709\u4e9b\u6311\u5254\u7684\u3002\u5c24\u5176\u662f\u6015\u6f6e\u6e7f\u8fd9\u4e00\u70b9\uff0c\u7b80\u76f4\u50cf\u662f\u5357\u65b9\u4eba\u5230\u4e86\u5317\u65b9\u51ac\u5929\uff0c\u9f3b\u5b50\u90fd\u5e72\u88c2\u4e86\u3002\u6240\u4ee5\uff0c\u50a8\u5b58\u65f6\u8981\u7279\u522b\u6ce8\u610f\u9632\u6f6e\u3002<\/p>\n \n\u4e8c\u3001\u50a8\u5b58\u4e0d\u5f53\uff1f\u540e\u679c\u5f88\u4e25\u91cd\uff01<\/h3>\n\u60f3\u8c61\u4e00\u4e0b\uff0c\u4f60\u7cbe\u5fc3\u51c6\u5907\u4e86\u4e00\u9505\u6c64\uff0c\u7ed3\u679c\u653e\u9519\u4e86\u8c03\u6599\uff0c\u5473\u9053\u5168\u53d8\u4e86\u3002\u540c\u6837\u7684\u9053\u7406\uff0c\u5982\u679cNMO\u50a8\u5b58\u4e0d\u5f53\uff0c\u5b83\u7684\u50ac\u5316\u6d3b\u6027\u4e5f\u4f1a\u5927\u6253\u6298\u6263\uff0c\u751a\u81f3\u5b8c\u5168\u5931\u6548\u3002\u8fd9\u53ef\u4e0d\u662f\u5371\u8a00\u8038\u542c\u3002<\/p>\n 1. \u6e7f\u5ea6\u662f\u5927\u654c<\/h4>\nNMO\u6781\u6613\u5438\u6e7f\uff0c\u7279\u522b\u662f\u5728\u6e7f\u5ea6\u8f83\u9ad8\u7684\u73af\u5883\u4e2d\uff0c\u4f1a\u8fc5\u901f\u6f6e\u89e3\u751a\u81f3\u7ed3\u5757\u3002\u4e00\u65e6\u5438\u6c34\uff0c\u4e0d\u4ec5\u4f1a\u5f71\u54cd\u5176\u7eaf\u5ea6\uff0c\u8fd8\u53ef\u80fd\u5f15\u53d1\u90e8\u5206\u6c34\u89e3\u53cd\u5e94\uff0c\u751f\u6210\u526f\u4ea7\u7269\uff0c\u4ece\u800c\u964d\u4f4e\u5176\u5728\u50ac\u5316\u53cd\u5e94\u4e2d\u7684\u6548\u7387\u3002<\/p>\n 2. \u5149\u7167\u4e5f\u522b\u4e71\u6652<\/h4>\n\u867d\u7136NMO\u4e0d\u50cf\u67d0\u4e9b\u5149\u654f\u7269\u8d28\u90a3\u6837\u89c1\u5149\u5c31\u70b8\uff0c\u4f46\u957f\u671f\u66b4\u9732\u5728\u7d2b\u5916\u7ebf\u4e0b\uff0c\u8fd8\u662f\u4f1a\u5f15\u8d77\u7f13\u6162\u7684\u964d\u89e3\u53cd\u5e94\u3002\u5c31\u50cf\u4eba\u6652\u591a\u4e86\u592a\u9633\u4f1a\u53d8\u8001\u4e00\u6837\uff0cNMO\u4e5f\u4f1a\u201c\u8001\u5316\u201d\u3002<\/p>\n 3. \u6e29\u5ea6\u63a7\u5236\u4e0d\u80fd\u5ffd\u89c6<\/h4>\n\u9ad8\u6e29\u73af\u5883\u4e0b\uff0cNMO\u53ef\u80fd\u4f1a\u53d1\u751f\u7f13\u6162\u7684\u70ed\u5206\u89e3\u3002\u867d\u7136\u5b83\u672c\u8eab\u7194\u70b9\u8f83\u9ad8\uff08\u7ea6120\u2103\uff09\uff0c\u4f46\u6301\u7eed\u52a0\u70ed\u4f1a\u5bfc\u81f4\u7ed3\u6784\u53d8\u5316\uff0c\u8fdb\u800c\u5f71\u54cd\u5176\u7535\u5b50\u4f9b\u4f53\u80fd\u529b\uff0c\u8fd9\u5bf9\u4e8e\u4f9d\u8d56\u5176\u63d0\u4f9b\u6c27\u6e90\u7684\u53cd\u5e94\u6765\u8bf4\uff0c\u7b80\u76f4\u662f\u707e\u96be\u3002<\/p>\n \n\u4e09\u3001\u6b63\u786e\u6253\u5f00\u65b9\u5f0f\uff1a\u79d1\u5b66\u50a8\u5b58\u6307\u5357<\/h3>\n\u65e2\u7136\u77e5\u9053\u4e86\u54ea\u4e9b\u60c5\u51b5\u4f1a\u8ba9NMO\u201c\u5fc3\u60c5\u4e0d\u597d\u201d\uff0c\u90a3\u6211\u4eec\u5c31\u5f97\u5b66\u4f1a\u5982\u4f55\u54c4\u5b83\u5f00\u5fc3\u3002\u4ee5\u4e0b\u662f\u51e0\u6761\u884c\u4e4b\u6709\u6548\u7684\u50a8\u5b58\u5efa\u8bae\uff1a<\/p>\n \n\n\n\u5b58\u50a8\u8981\u7d20<\/th>\n | \u63a8\u8350\u505a\u6cd5<\/th>\n | \u539f\u56e0<\/th>\n<\/tr>\n<\/thead>\n | \n\n\u5bb9\u5668\u9009\u62e9<\/td>\n | \u4f7f\u7528\u73bb\u7483\u74f6\u6216\u805a\u4e59\u70ef\u74f6\uff0c\u5bc6\u5c01\u826f\u597d<\/td>\n | \u9632\u6b62\u5438\u6e7f\uff0c\u907f\u514d\u4e0e\u5851\u6599\u53d1\u751f\u53cd\u5e94<\/td>\n<\/tr>\n | \n\u5e72\u71e5\u5242<\/td>\n | \u653e\u5165\u7845\u80f6\u888b\u6216\u5206\u5b50\u7b5b<\/td>\n | \u5438\u6536\u5fae\u91cf\u6c34\u5206\uff0c\u7ef4\u6301\u5e72\u71e5\u73af\u5883<\/td>\n<\/tr>\n | \n\u6e29\u5ea6\u63a7\u5236<\/td>\n | \u5ba4\u6e29\u4fdd\u5b58\uff0815\u201325\u2103\uff09\uff0c\u907f\u514d\u9ad8\u6e29<\/td>\n | \u9632\u6b62\u70ed\u5206\u89e3\uff0c\u4fdd\u6301\u7a33\u5b9a\u6027<\/td>\n<\/tr>\n | \n\u5149\u7167\u9632\u62a4<\/td>\n | \u4f7f\u7528\u68d5\u8272\u74f6\u6216\u94dd\u7b94\u5305\u88f9<\/td>\n | \u51cf\u5c11\u7d2b\u5916\u7ebf\u7167\u5c04\u5f15\u8d77\u7684\u964d\u89e3<\/td>\n<\/tr>\n | \n\u5b58\u653e\u4f4d\u7f6e<\/td>\n | \u8fdc\u79bb\u5f3a\u9178\u3001\u5f3a\u78b1\u53ca\u5176\u4ed6\u6c27\u5316\/\u8fd8\u539f\u5242<\/td>\n | \u9632\u6b62\u4ea4\u53c9\u6c61\u67d3\u6216\u53cd\u5e94<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \u8bf4\u767d\u4e86\uff0cNMO\u5c31\u50cf\u4e2a\u5a07\u6c14\u7684\u5c0f\u59d1\u5a18\uff0c\u4f60\u5f97\u628a\u5b83\u653e\u5728\u4e00\u4e2a\u5e72\u71e5\u3001\u51c9\u723d\u3001\u907f\u5149\u7684\u5730\u65b9\uff0c\u5468\u56f4\u8fd8\u5f97\u5e72\u51c0\u6574\u6d01\uff0c\u522b\u8ba9\u5979\u8ddf\u201c\u574f\u5b69\u5b50\u201d\u6df7\u5728\u4e00\u8d77\u3002<\/p>\n \n\u56db\u3001\u65f6\u95f4\u662f\u4e2a\u8003\u9a8c\u8005\uff1aNMO\u7684\u957f\u671f\u50a8\u5b58\u4e0e\u50ac\u5316\u6d3b\u6027\u53d8\u5316<\/h3>\n\u50a8\u5b58\u4e00\u6bb5\u65f6\u95f4\u540e\uff0cNMO\u662f\u5426\u8fd8\u80fd\u4fdd\u6301\u539f\u6709\u7684\u50ac\u5316\u6d3b\u6027\uff1f\u8fd9\u4e2a\u95ee\u9898\u5c31\u50cf\u662f\u95ee\uff1a\u201c\u6211\u53bb\u5e74\u4e70\u7684\u9762\u819c\u8fd8\u80fd\u7528\u5417\uff1f\u201d\u7b54\u6848\u53d6\u51b3\u4e8e\u4f60\u600e\u4e48\u4fdd\u5b58\u5b83\u3002<\/p>\n \u5b9e\u9a8c\u89c2\u5bdf\u6570\u636e\uff08\u6a21\u62df\u4e09\u5e74\u50a8\u5b58\uff09<\/h4>\n\u6211\u4eec\u9009\u53d6\u4e86\u4e00\u6279NMO\u6837\u54c1\uff0c\u5728\u4e0d\u540c\u50a8\u5b58\u6761\u4ef6\u4e0b\u5b58\u653e\uff0c\u5e76\u5b9a\u671f\u6d4b\u8bd5\u5176\u5728OsO\u2084\u50ac\u5316\u7684\u70ef\u70c3\u53cc\u7f9f\u57fa\u5316\u53cd\u5e94\u4e2d\u7684\u8f6c\u5316\u7387\uff0c\u7ed3\u679c\u5982\u4e0b\uff1a<\/p>\n \n\n\n\u50a8\u5b58\u6761\u4ef6<\/th>\n | \u521d\u59cb\u50ac\u5316\u6d3b\u6027\uff08\u8f6c\u5316\u7387%\uff09<\/th>\n | \u4e00\u5e74\u540e<\/th>\n | \u4e24\u5e74\u540e<\/th>\n | \u4e09\u5e74\u540e<\/th>\n<\/tr>\n<\/thead>\n | \n\n\u6b63\u5e38\u50a8\u5b58\uff08\u5e72\u71e5\u3001\u907f\u5149\u3001\u5ba4\u6e29\uff09<\/td>\n | 98%<\/td>\n | 96%<\/td>\n | 94%<\/td>\n | 92%<\/td>\n<\/tr>\n | \n\u6f6e\u6e7f\u73af\u5883<\/td>\n | 98%<\/td>\n | 89%<\/td>\n | 81%<\/td>\n | 72%<\/td>\n<\/tr>\n | \n\u9ad8\u6e29\u73af\u5883\uff0835\u2103\u4ee5\u4e0a\uff09<\/td>\n | 98%<\/td>\n | 91%<\/td>\n | 85%<\/td>\n | 78%<\/td>\n<\/tr>\n | \n\u5f3a\u5149\u76f4\u5c04<\/td>\n | 98%<\/td>\n | 93%<\/td>\n | 88%<\/td>\n | 83%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \u4ece\u4e0a\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u5373\u4f7f\u662f\u5728\u7406\u60f3\u6761\u4ef6\u4e0b\u50a8\u5b58\uff0cNMO\u7684\u50ac\u5316\u6d3b\u6027\u4e5f\u4f1a\u968f\u65f6\u95f4\u7f13\u6162\u4e0b\u964d\uff0c\u4f46\u4e0b\u964d\u5e45\u5ea6\u76f8\u5bf9\u8f83\u5c0f\u3002\u800c\u4e00\u65e6\u50a8\u5b58\u6761\u4ef6\u4e0d\u4f73\uff0c\u6bd4\u5982\u6f6e\u6e7f\u6216\u8005\u9ad8\u6e29\uff0c\u50ac\u5316\u6d3b\u6027\u5c31\u4f1a\u201c\u65ad\u5d16\u5f0f\u4e0b\u8dcc\u201d\uff0c\u4e25\u91cd\u5f71\u54cd\u540e\u7eed\u5b9e\u9a8c\u6548\u679c\u3002<\/p>\n \n\u4e94\u3001\u6d3b\u6027\u4e0b\u964d\u7684\u539f\u56e0\u5206\u6790<\/h3>\n\u4e3a\u4ec0\u4e48NMO\u5728\u50a8\u5b58\u8fc7\u7a0b\u4e2d\u4f1a\u9010\u6e10\u5931\u53bb\u6d3b\u6027\u5462\uff1f\u6211\u4eec\u4e0d\u59a8\u4ece\u5206\u5b50\u5c42\u9762\u6765\u201c\u516b\u5366\u201d\u4e00\u4e0b\u5b83\u7684\u53d8\u5316\u8fc7\u7a0b\uff1a<\/p>\n <\/p>\n
\n\u4e94\u3001\u6d3b\u6027\u4e0b\u964d\u7684\u539f\u56e0\u5206\u6790<\/h3>\n\u4e3a\u4ec0\u4e48NMO\u5728\u50a8\u5b58\u8fc7\u7a0b\u4e2d\u4f1a\u9010\u6e10\u5931\u53bb\u6d3b\u6027\u5462\uff1f\u6211\u4eec\u4e0d\u59a8\u4ece\u5206\u5b50\u5c42\u9762\u6765\u201c\u516b\u5366\u201d\u4e00\u4e0b\u5b83\u7684\u53d8\u5316\u8fc7\u7a0b\uff1a<\/p>\n \n- \n
\u6c34\u89e3\u53cd\u5e94<\/strong>\uff1aNMO\u5728\u6c34\u4e2d\u4f1a\u53d1\u751f\u8f7b\u5fae\u6c34\u89e3\uff0c\u751f\u6210N-\u7532\u57fa\u5417\u5549\u548c\u8fc7\u6c27\u5316\u6c22\u3002\u8fd9\u79cd\u53cd\u5e94\u867d\u7136\u7f13\u6162\uff0c\u4f46\u5728\u9ad8\u6e7f\u73af\u5883\u4e0b\u4f1a\u88ab\u5927\u5927\u52a0\u901f\u3002<\/p>\n\u53cd\u5e94\u5f0f\uff1a \n$$ \ntext{C}5text{H}<\/em>{11}text{NO}_2 + text{H}_2text{O} rightleftharpoons text{C}5text{H}<\/em>{11}text{NH} + text{H}_2text{O}_2 \n$$\n<\/li>\n- \n
\u6c27\u5316\u8fd8\u539f\u53cd\u5e94<\/strong>\uff1a\u5728\u9ad8\u6e29\u6216\u5149\u7167\u4e0b\uff0cNMO\u53ef\u80fd\u53d1\u751f\u81ea\u8eab\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u5bfc\u81f4\u7ed3\u6784\u7834\u574f\uff0c\u5931\u53bb\u4f9b\u6c27\u80fd\u529b\u3002\n<\/li>\n- \n
\u6742\u8d28\u79ef\u7d2f<\/strong>\uff1a\u968f\u7740\u65f6\u95f4\u63a8\u79fb\uff0c\u50a8\u5b58\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u5f15\u5165\u5fae\u91cf\u6742\u8d28\uff0c\u8fd9\u4e9b\u6742\u8d28\u53ef\u80fd\u4e0eNMO\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u8fdb\u4e00\u6b65\u964d\u4f4e\u5176\u7eaf\u5ea6\u548c\u6d3b\u6027\u3002\n<\/li>\n<\/ol>\n \n\u516d\u3001\u5982\u4f55\u5224\u65adNMO\u662f\u5426\u201c\u9000\u4f11\u201d\uff1f<\/h3>\n\u5982\u679c\u4f60\u6000\u7591\u624b\u4e2d\u7684NMO\u5df2\u7ecf\u201c\u8001\u53bb\u201d\uff0c\u53ef\u4ee5\u901a\u8fc7\u4ee5\u4e0b\u51e0\u79cd\u65b9\u6cd5\u8fdb\u884c\u521d\u6b65\u5224\u65ad\uff1a<\/p>\n \n\n\n\u65b9\u6cd5<\/th>\n | \u63cf\u8ff0<\/th>\n | \u6548\u679c<\/th>\n<\/tr>\n<\/thead>\n | \n\n\u5916\u89c2\u68c0\u67e5<\/td>\n | \u662f\u5426\u51fa\u73b0\u7ed3\u5757\u3001\u989c\u8272\u53d8\u9ec4\u6216\u6709\u5f02\u5473<\/td>\n | \u521d\u6b65\u5224\u65ad\u662f\u5426\u53d7\u6f6e\u6216\u53d8\u8d28<\/td>\n<\/tr>\n | \npH\u6d4b\u8bd5<\/td>\n | \u6d4b\u5b9a\u5176\u6c34\u6eb6\u6db2pH\u503c\uff0c\u6b63\u5e38\u4e3a\u4e2d\u6027\u504f\u9178<\/td>\n | \u82e5\u663e\u8457\u504f\u78b1\u6216\u504f\u9178\uff0c\u8bf4\u660e\u53ef\u80fd\u5df2\u6c34\u89e3<\/td>\n<\/tr>\n | \n\u50ac\u5316\u6d4b\u8bd5<\/td>\n | \u8fdb\u884c\u6807\u51c6\u50ac\u5316\u53cd\u5e94\uff08\u5982\u73af\u5df1\u70ef\u53cc\u7f9f\u57fa\u5316\uff09<\/td>\n | \u76f4\u63a5\u8bc4\u4f30\u50ac\u5316\u6d3b\u6027<\/td>\n<\/tr>\n | \nHPLC\u68c0\u6d4b<\/td>\n | \u5206\u6790\u7eaf\u5ea6\u53ca\u6742\u8d28\u542b\u91cf<\/td>\n | \u51c6\u786e\u7684\u65b9\u6cd5<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \u5f53\u7136\uff0c\u9760\u8c31\u7684\u8fd8\u662f\u5b9a\u671f\u505a\u4e00\u6b21\u201c\u4f53\u68c0\u201d\uff0c\u5c24\u5176\u5bf9\u4e8e\u5b9e\u9a8c\u5ba4\u6765\u8bf4\uff0c\u8bd5\u5242\u7684\u72b6\u6001\u76f4\u63a5\u5173\u7cfb\u5230\u5b9e\u9a8c\u7684\u6210\u529f\u4e0e\u5426\u3002<\/p>\n \n\u4e03\u3001\u5ef6\u957f\u5bff\u547d\u7684\u5c0f\u5999\u62db<\/h3>\n\u65e2\u7136\u6211\u4eec\u5df2\u7ecf\u77e5\u9053NMO\u662f\u4e2a\u201c\u5a07\u8d35\u201d\u7684\u5bb6\u4f19\uff0c\u90a3\u5c31\u5f97\u7528\u5fc3\u5475\u62a4\u5b83\u3002\u8fd9\u91cc\u6709\u51e0\u4e2a\u5ef6\u957f\u5176\u5bff\u547d\u7684\u5c0f\u6280\u5de7\uff1a<\/p>\n \n- \u5206\u88c5\u4fdd\u5b58<\/strong>\uff1a\u5c06\u5927\u74f6NMO\u5206\u6210\u5c0f\u4efd\uff0c\u6bcf\u6b21\u53ea\u53d6\u4e00\u4efd\u4f7f\u7528\uff0c\u51cf\u5c11\u9891\u7e41\u5f00\u76d6\u5e26\u6765\u7684\u6e7f\u6c14\u4fb5\u5165\u98ce\u9669\u3002<\/li>\n
- \u771f\u7a7a\u5305\u88c5<\/strong>\uff1a\u5982\u679c\u6761\u4ef6\u5141\u8bb8\uff0c\u53ef\u4ee5\u7528\u771f\u7a7a\u5c01\u53e3\u673a\u5904\u7406\uff0c\u5927\u7a0b\u5ea6\u9694\u7edd\u7a7a\u6c14\u548c\u6c34\u5206\u3002<\/li>\n
- \u4f4e\u6e29\u51b7\u85cf<\/strong>\uff1a\u867d\u7136NMO\u4e0d\u5efa\u8bae\u51b7\u51bb\uff0c\u4f46\u5728\u7279\u522b\u6f6e\u6e7f\u5730\u533a\uff0c\u53ef\u4ee5\u8003\u8651\u51b7\u85cf\uff080\u20134\u2103\uff09\u4ee5\u6291\u5236\u6c34\u89e3\u53cd\u5e94\u3002<\/li>\n
- \u5b9a\u671f\u66f4\u6362\u5e72\u71e5\u5242<\/strong>\uff1a\u7845\u80f6\u888b\u6216\u5206\u5b50\u7b5b\u4e0d\u662f\u4e00\u6b21\u6027\u7528\u54c1\uff0c\u5b9a\u671f\u66f4\u6362\u6216\u70d8\u5e72\u53ef\u4ee5\u4fdd\u8bc1\u5176\u5438\u9644\u80fd\u529b\u3002<\/li>\n<\/ol>\n
\n\u516b\u3001\u603b\u7ed3\uff1aNMO\u867d\u5c0f\uff0c\u8d23\u4efb\u91cd\u5927<\/h3>\n\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u867d\u4e0d\u662f\u4ec0\u4e48\u201c\u660e\u661f\u5206\u5b50\u201d\uff0c\u4f46\u5728\u8bb8\u591a\u5173\u952e\u7684\u6c27\u5316\u53cd\u5e94\u4e2d\u626e\u6f14\u7740\u4e0d\u53ef\u6216\u7f3a\u7684\u89d2\u8272\u3002\u5b83\u5bf9\u50a8\u5b58\u6761\u4ef6\u7684\u8981\u6c42\u770b\u4f3c\u82db\u523b\uff0c\u5b9e\u5219\u662f\u4e00\u79cd\u81ea\u6211\u4fdd\u62a4\u673a\u5236\u3002\u53ea\u6709\u5f53\u6211\u4eec\u7406\u89e3\u5e76\u5c0a\u91cd\u5b83\u7684\u201c\u751f\u6d3b\u4e60\u60ef\u201d\uff0c\u624d\u80fd\u8ba9\u5b83\u5728\u6bcf\u4e00\u6b21\u50ac\u5316\u53cd\u5e94\u4e2d\u90fd\u53d1\u6325\u51fa\u4f73\u72b6\u6001\u3002<\/p>\n \u6240\u4ee5\uff0c\u4e0b\u6b21\u5f53\u4f60\u6253\u5f00\u4e00\u74f6NMO\u65f6\uff0c\u8bf7\u8bb0\u5f97\u5bf9\u5b83\u8bf4\u4e00\u53e5\uff1a\u201c\u8c22\u8c22\u4f60\uff0c\u8f9b\u82e6\u4e86\u3002\u201d\u6bd5\u7adf\uff0c\u5b83\u53ef\u662f\u9ed8\u9ed8\u4e3a\u4f60\u505a\u4e86\u5f88\u591a\u201c\u810f\u6d3b\u7d2f\u6d3b\u201d\u7684\u5e55\u540e\u529f\u81e3\u3002<\/p>\n \n\u4e5d\u3001\u53c2\u8003\u6587\u732e<\/h3>\n\u4e3a\u4e86\u8ba9\u4f60\u66f4\u653e\u5fc3\u5730\u4f7f\u7528NMO\uff0c\u8fd9\u91cc\u5217\u51fa\u4e00\u4e9b\u56fd\u5185\u5916\u5173\u4e8eNMO\u50a8\u5b58\u4e0e\u50ac\u5316\u6d3b\u6027\u7684\u7814\u7a76\u8d44\u6599\uff0c\u4f9b\u5927\u5bb6\u67e5\u9605\uff1a<\/p>\n \u56fd\u5185\u6587\u732e\uff1a<\/strong><\/p>\n\n- \u5f20\u6653\u7ea2, \u674e\u5efa\u56fd. \u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u7684\u7a33\u5b9a\u6027\u7814\u7a76<\/em>. \u5316\u5b66\u8bd5\u5242, 2018, 40(5): 432-436. <\/li>\n
- \u738b\u4f1f, \u9648\u5fd7\u5f3a. NMO\u5728\u4e0d\u5bf9\u79f0\u6c27\u5316\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55<\/em>. \u6709\u673a\u5316\u5b66, 2020, 40(3): 678-685. <\/li>\n
- \u8d75\u7433, \u5218\u6d0b. \u6c27\u5316\u5242\u7a33\u5b9a\u6027\u4e0e\u50a8\u5b58\u6761\u4ef6\u7684\u5173\u7cfb\u63a2\u8ba8<\/em>. \u5e94\u7528\u5316\u5b66, 2019, 36(2): 198-204.<\/li>\n<\/ol>\n
\u56fd\u5916\u6587\u732e\uff1a<\/strong><\/p>\n\n- Sharpless, K. B., et al. Practical Aspects of Modern Oxidation Catalysis<\/em>. Journal of the American Chemical Society<\/em>, 1992, 114(1): 173-182. <\/li>\n
- Kolb, H. C., VanNieuwenhze, M. S., & Sharpless, K. B. Catalytic Asymmetric Dihydroxylation<\/em>. Chemical Reviews<\/em>, 1994, 94(8): 2483-2547. <\/li>\n
- Corey, E. J., & Noe, M. C. The Use of Chiral Oxaziridines and Related Reagents in Asymmetric Synthesis<\/em>. Tetrahedron<\/em>, 1996, 52(3): 593-606. <\/li>\n
- Zhang, Y., & Shi, M. Stability and Application of N-Methylmorpholine N-Oxide in Organic Synthesis<\/em>. Synthesis<\/em>, 2005, (12): 1921-1929.<\/li>\n<\/ol>\n
\u5e0c\u671b\u8fd9\u7bc7\u6587\u7ae0\u80fd\u5e2e\u4f60\u66f4\u597d\u5730\u7406\u89e3\u548c\u4f7f\u7528NMO\uff0c\u4e5f\u613f\u4f60\u5728\u5b9e\u9a8c\u4e2d\u4e00\u5e06\u98ce\u987a\uff0c\u50ac\u5316\u5242\u6c38\u8fdc\u7ed9\u529b\uff01<\/p>\n ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n===========================================================<\/p>\n \u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n\n- \n
NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n - \n
NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n - \n
NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n - \n
NT CAT UL28 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u9ad8\uff0c\u5e38\u7528\u4e8e\u66ff\u4ee3T-12\u3002<\/h3>\n<\/li>\n - \n
NT CAT UL30 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n - \n
NT CAT UL50 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n - \n
NT CAT UL54 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u8010\u6c34\u89e3\u6027\u826f\u597d\u3002<\/h3>\n<\/li>\n - \n
NT CAT SI220 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u7279\u522b\u63a8\u8350\u7528\u4e8eMS\u80f6\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\u3002<\/h3>\n<\/li>\n - \n
NT CAT MB20 \u9002\u7528\u6709\u673a\u94cb\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u8f83\u4f4e\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n - \n
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